Document Type : Review Paper

Authors

1 Department of Civil Engineering, University of Birjand, Birjand, Iran

2 Department of Chemistry, University of Birjand, Birjand, Iran

Abstract

Today, quality monitoring of water resources played an influential role in its exploitation and use. Water sources usually contain heavy metals in minor concentrations. The research showed various methods of removing heavy metals in aqueous solutions, such as chemical reduction, ion exchange, adsorption, etc. Hence, the widespread applications of nanotechnology to remove toxic pollutants from different contaminated water sources are known. In this study, while the existence of other methods for pollutants elimination from water, the use of iron nanoparticles was investigated. Eco-friendly and cost-effective nanomaterials are vital to ultimately removing contaminants from water. Meanwhile, iron nanoparticles are available, cheap, and practical in water and wastewater treatment. Therefore, Nano Zero-Valeant Iron (nZVI) with high surface area, nanoscale particle size, unique catalytic activity, more reactivity than bulk iron, and mobility in the underground has attracted significant consideration due to their performance in removing pollutants from aqueous solutions. Since nZVI could have aggregated, various linkers have been used to stabilize these particles on the substrate, and the use of some linkers to support these nanoparticles was examined. The results showed that hydrophilic and biodegradable linkers such as Starch, Carboxymethyl cellulose (CMC), Polyethylene glycol (PEG), Polyacrylamide (PAM), and Polyvinylpyrrolidone (PVP) could increase the speed of chemical reaction in reducing pollutants from water. Because linkers often had different functional groups that could enhance the stabilizing of these particles on the substrate. Among these linkers, PVP, as a hydrophilic, cheap, and biodegradable polymer, has performed an excellent function in supporting nZVI.

Keywords

Main Subjects

Ajith, M. P., Aswathi, M., Priyadarshini, E., & Rajamani, P. (2021). Recent innovations of nanotechnology in water treatment: A comprehensive review. Bioresource Technology, 342, 126000-126011.
Al-Amshawee, S., Yunus, M. Y. B. M., Azoddein, A. A. M., Hassell, D. G., Dakhil, I. H., & Hasan, H. A. (2020). Electrodialysis desalination for water and wastewater: A review. Chemical Engineering Journal, 380, 122231-122240.
Almasian, A., Giahi, M., Fard, G. C., Dehdast, S. A., & Maleknia, L. (2018). Removal of heavy metal ions by modified PAN/PANI-nylon core-shell nanofibers membrane: Filtration performance, antifouling and regeneration behavior. Chemical Engineering Journal, 351, 1166-1178.
Barzegar, G., Jorfi, S., Zarezade, V., Khatebasreh, M., Mehdipour, F., & Ghanbari, F. (2018). 4-Chlorophenol degradation using ultrasound/peroxymonosulfate/nanoscale zero valent iron: reusability, identification of degradation intermediates and potential application for real wastewater. Chemosphere, 201, 370-379.
Brasili, E., Bavasso, I., Petruccelli, V., Vilardi, G., Valletta, A., Dal Bosco, C., ... and Di Palma, L. (2020). Remediation of hexavalent chromium contaminated water through zero-valent iron nanoparticles and effects on tomato plant growth performance. Scientific reports, 10, 1920-1931.
Chakraborty, R., Asthana, A., Singh, A. K., Jain, B., & Susan, A. B. H. (2022). Adsorption of heavy metal ions by various low-cost adsorbents: a review. International Journal of Environmental Analytical Chemistry, 102, 342-379.
Chen, L., Yuan, T., Ni, R., Yue, Q., & Gao, B. (2019). Multivariate optimization of ciprofloxacin removal by Polyvinylpyrrolidone stabilized NZVI/Cu bimetallic particles. Chemical Engineering Journal, 365, 183-192.
Christy, E. J. S., Rajeswari, A., Gopi, S., & Pius, A. (2020). Chitin and chitosan-based aerogels. Handbook of Chitin and Chitosan.
Connolly, C. T., Cardenas, M. B., Burkart, G. A., Spencer, R. G., & McClelland, J. W. (2020). Groundwater as a major source of dissolved organic matter to Arctic coastal waters. Nature Communications, 11, 1479-1487.
Devi, D., Julkapli, N. M., Sagadevan, S., & Johan, M. R. (2023). Eco-friendly green synthesis approach and evaluation of environmental and biological applications of Iron oxide nanoparticles. Inorganic Chemistry Communications, 152, 110700-110715.
Eljamal, R., Eljamal, O., & Matsunaga, N. (2018, October). Enhancement of the Reduction and Adsorption Mechanism of nZVI using an effective polyacrylamide as a nonionic polymer, In Proceedings of the Sciences (IEICES) of Fukuoka, Japan Conference.
Eljamal, R., Eljamal, O., Maamoun, I., Yilmaz, G., & Sugihara, Y. (2020). Enhancing the characteristics and reactivity of nZVI: Polymers effect and mechanisms. Journal of Molecular Liquids, 315, 113714-113720.
Elkady, M., Shokry, H., El-Sharkawy, A., El-Subruiti, G., & Hamad, H. (2019). New insights into the activity of green supported nanoscale zero-valent iron composites for enhanced acid blue-25 dye synergistic. decolorization from aqueous medium. Journal of Molecular Liquids, 294, 111628-111638.
Elsaid, K., Olabi, A. G., Abdel-Wahab, A., Elkamel, A., Alami, A. H., Inayat, A., ... and Abdelkareem, M. A. (2023). Membrane processes for environmental remediation of nanomaterials: Potentials and challenges. Science of the Total Environment, 879, 162569-162584.
Fida, M., Li, P., Wang, Y., Alam, S. K., & Nsabimana, A. (2022). Water contamination and human health risks in Pakistan: a review. Exposure and Health, 14, 1-21.
Fu, F., Dionysiou, D. D., & Liu, H. (2014). The use of zero-valent iron for groundwater remediation and wastewater treatment: a review. Journal of hazardous materials, 267, 194-205.
Habibi, Y. (2014). Key advances in the chemical modification of nanocelluloses. Chemical Society Reviews, 43, 1519-1542.
Hemmat, K., Khodabakhshi, M. R., & Zeraatkar Moghaddam, A. (2021). Synthesis of nanoscale zero‐valent iron modified graphene oxide nanosheets and its application for removing tetracycline antibiotic: Response surface methodology. Applied Organometallic Chemistry, 35, 6059-6070.
Idrees, A., Shan, A., Ali, M., Abbas, Z., Shahzad, T., Hussain, S., & Lyu, S. (2021). Highly efficient degradation of trichloroethylene in groundwater based on persulfate activation by polyvinylpyrrolidone functionalized Fe/Cu bimetallic nanoparticles. Journal of Environmental Chemical Engineering, 9, 105341-105353.
Jiao, C., Tan, X., Lin, A., & Yang, W. (2019). Preparation of activated carbon supported bead string structure nano zero valent iron in a polyethylene glycol-aqueous solution and its efficient treatment of Cr (VI) wastewater. Molecules, 25, 47-57.
Kordbacheh, F., & Heidari, G. (2023). Water Pollutants and Approaches for their Removal. Materials Chemistry Horizons, 2, 139-153.‏
Kumari, B., & Dutta, S. (2020). Integrating starch encapsulated nanoscale zero-valent iron for better chromium removal performance. Journal of Water Process Engineering, 37, 101370-101379.
Lei, C., Sun, Y., Khan, E., Chen, S. S., Tsang, D. C., Graham, N. J., ... and Li, X. D. (2018). Removal of chlorinated organic solvents from hydraulic fracturing wastewater by bare and entrapped nanoscale zero-valent iron. Chemosphere, 196, 9-17.
Li, Y. Y., Wang, B., Ma, M. G., & Wang, B. (2018). Review of recent development on preparation, properties, and applications of cellulose-based functional materials. International Journal of Polymer Science, 218, 1-18.
Liu, J., Liu, A., Guo, J., Zhou, T., & Zhang, W. X. (2021). Enhanced aggregation and sedimentation of nanoscale zero-valent iron (nZVI) with polyacrylamide modification. Chemosphere, 263, 127875-127883.
Liu, Y., Zhang, H., Ding, Y., Hu, N., & Ding, D. (2023). Preparation of carboxy methyl cellulose stabilized nano-sized zero-valent iron and its properties for in situ remediation of groundwater in areas after acid in situ leach uranium mining. Environmental Science: Water Research and Technology, 9, 1480-1490.
Lou, Y., Cai, Y., Tong, Y., Hsieh, L., Li, X., Xu, W., ... and Lou, L. (2019). Interaction between pollutants during the removal of polychlorinated biphenyl-heavy metal combined pollution by modified nanoscale zero- valent iron. Science of the total environment, 673, 120-127.
Malekzadeh, M., Nejaei, A., Baneshi, M. M., Kokhdan, E. P., & Bardania, H. (2018). The use of starch‐modified magnetic Fe0 nanoparticles for naphthalene adsorption from water samples: Adsorption isotherm, kinetic and thermodynamic studies. Applied Organometallic Chemistry, 32, 4434-4444.
Mohamed, H. H., Besisa, D. H., Besisa, N., & Youssef, T. E. (2023). Green magnetite nanostructure for removing organic pollutants from water. Materials Science and Engineering: B, 296, 116634-116643.
Nasrollahzadeh, M., Sajjadi, M., Iravani, S., & Varma, R. S. (2021). Starch, cellulose, pectin, gum, alginate, chitin and chitosan derived (nano) materials for sustainable water treatment: A review. Carbohydrate polymers, 251, 116986-116996.
Ohale, P. E., Igwegbe, C. A., Iwuozor, K. O., Emenike, E. C., Obi, C. C., & Białowiec, A. (2023). A review of the adsorption method for norfloxacin reduction from aqueous media. MethodsX, 10, 102180-102201.
Ozaki, H., Ichise, H., Kitaura, E., Yaginuma, Y., Yoda, M., Kuno, K., & Watanabe, I. (2019). Immutable heavy metal pollution before and after change in industrial waste treatment procedure. Scientific reports, 9, 1-12.
Pasinszki, T., & Krebsz, M. (2020). Synthesis and application of zero-valent iron nanoparticles in water treatment, environmental remediation, catalysis, and their biological effects. Nanomaterials, 10, 917-926.
Peng, H., & Guo, J. (2020). Removal of chromium from wastewater by membrane filtration, chemical precipitation, ion exchange, adsorption electrocoagulation, electrochemical reduction, electrodialysis, electrodeionization, photocatalysis and nanotechnology: a review. Environmental Chemistry Letters, 18, 2055-2068.
Qasem, N. A., Mohammed, R. H., & Lawal, D. U. (2021). Removal of heavy metal ions from wastewater: A comprehensive and critical review. Npj Clean Water, 4, 1-15.
Romeh, A. A. A. (2023). Main Green Nanomaterials for Water Remediation. Green Nano remediation: Sustainable Management of Environmental Pollution
Saleh, T. A., Mustaqeem, M., & Khaled, M. (2022). Water treatment technologies in removing heavy metal ions from wastewater: A review. Environmental Nanotechnology, Monitoring and Management17, 100617-100627.
Shad, S., Belinga-Desaunay-Nault, M. F. A., Bashir, N., & Lynch, I. (2020). Removal of contaminants from canal water using microwave synthesized zero valent iron nanoparticles. Environmental Science: Water Research and Technology, 6, 3057-3065.
Shamshirgaran, R., Malakooti, R., Akbarpour, A., & Moghaddam, A. Z. (2022). Fabrication of Polyvinylpyrrolidone‐Stabilized Nano Zero‐Valent Iron Supported by Hydrophilic Biochar for Efficient Cr (VI) Removal from Groundwater. ChemistrySelect, 7, 1-11.
Sharma, A. K., Devan, R. S., Arora, M., Kumar, R., Ma, Y. R., & Babu, J. N. (2018). Reductive-co-precipitated cellulose immobilized zerovalent iron nanoparticles in ionic liquid/water for Cr (VI) adsorption. Cellulose, 25, 5259-5275.
Shrestha, R., Ban, S., Devkota, S., Sharma, S., Joshi, R., Tiwari, A. P., ... and Joshi, M. K. (2021). Technological trends in heavy metals removal from industrial wastewater: A review. Journal of Environmental Chemical Engineering, 9, 105688-105706.
Sidorenko, A., Gutul, T., Dvornikov, D., Şeker, M. G., Arit, T., Gutul, E., ... and Vaseashta, A. (2022). Synthesis of nZVI/PVP nanoparticles for bioremediation applications. Bioremediation Journal, 26, 162-170.
Siti, N., Mohd, H., Md, L. K., & Shamsul, I. (2013). Adsorption process of heavy metals by low-cost adsorbent: a review. World Applied Sciences Journal, 28, 1518-1530.
Stenina, I., Golubenko, D., Nikonenko, V., & Yaroslavtsev, A. (2020). Selectivity of transport processes in ion-exchange membranes: Relationship with the structure and methods for its improvement. International Journal of Molecular Sciences, 21, 5517-5526.
Tian, H., Liang, Y., Yang, D., & Sun, Y. (2020). Characteristics of PVP–stabilised NZVI and application to dechlorination of soil–sorbed TCE with ionic surfactant. Chemosphere, 239, 124807.
Wang, P., Fu, F., & Liu, T. (2021). A review of the new multifunctional nano zero-valent iron composites for wastewater treatment: Emergence, preparation, optimization and mechanism. Chemosphere, 285, 131435-131445.
Wang, S., Zhong, D., Xu, Y., & Zhong, N. (2022). Removal of Hexavalent Chromium from Simulated Wastewater by Polyethylene Glycol–Modified D201 Resin-Supported Nanoscale Zero-Valent Iron. Water, Air, and Soil Pollution, 233, 1-15.
Wang, W., Li, S., Lei, H., Pan, B., & Zhang, W. X. (2015). Enhanced separation of nanoscale zero-valent iron (nZVI) using polyacrylamide: performance, characterization and implication. Chemical Engineering Journal, 260, 616-622.
Wu, H., Wei, W., Xu, C., Meng, Y., Bai, W., Yang, W., & Lin, A. (2020). Polyethylene glycol-stabilized nano zero-valent iron supported by biochar for highly efficient removal of Cr (VI). Ecotoxicology and Environmental Safety, 188, 109902-109912.
Xu, W., Li, Z., Shi, S., Qi, J., Cai, S., Yu, Y., ... and He, F. (2020). Carboxymethyl cellulose stabilized and sulfidated nanoscale zero-valent iron: Characterization and trichloroethene dechlorination. Applied Catalysis B: Environmental, 262, 118303-118312.
Yahyaeian, M., Zeraatkar Moghaddam, A., & Fooladi, E. (2023). Use of Efficient and Low-Cost    Trimetallic Based on Zero-Valent Iron, Immobilized on Bentonite Surface to Remove Sunset Yellow and Tartrazine Dyes Using Response Surface Optimization Method. Water, Air, and Soil Pollution, 234, 79-88.
Yang, C., Ge, C., Li, X., Li, L., Wang, B., Lin, A., & Yang, W. (2021). Does soluble starch improve the removal of Cr (VI) by nZVI loaded on biochar. Ecotoxicology and Environmental Safety, 208, 111552-111561.
Yu, Q., Guo, J., Muhammad, Y., Li, Q., Lu, Z., Yun, J., & Liang, Y. (2020). Mechanisms of enhanced hexavalent chromium removal from groundwater by sodium carboxymethyl cellulose stabilized zerovalent iron nanoparticles. Journal of Environmental Management, 276, 111245-111254.
Zafar, A. M., Javed, M. A., Hassan, A. A., & Mohamed, M. M. (2021). Groundwater remediation using zero-valent iron nanoparticles (nZVI). Groundwater for Sustainable Development, 15, 100694-100704.
Zhang, S., Lyu, H., Tang, J., Song, B., Zhen, M., & Liu, X. (2019). A novel biochar supported CMC stabilized nano zero-valent iron composite for hexavalent chromium removal from water. Chemosphere, 217, 686-694.
Zhao, J., Yang, X., Liang, G., Wang, Z., Li, S., Wang, Z., & Xie, X. (2020). Effective removal of two fluoroquinolone antibiotics by PEG-4000 stabilized nanoscale zero-valent iron supported onto zeolite (PZ-NZVI). Science of the Total Environment, 710, 136289-136299.
Zhao, K., Yang, L., Qian, L., Zhang, Y., Hou, J., Christie, P., ... and Qi, P. (2022). Elimination of Chromium (VI) and Vanadium (V) from Waters by Carboxymethylcellulose-Stabilized Amorphous Nanoscale Zero-Valent Iron. Water, Air, and Soil Pollution, 233, 1-14.
Zhao, L., Zhao, Y., Yang, B., & Teng, H. (2019). Application of carboxymethyl cellulose–stabilized sulfidated nano zerovalent iron for removal of Cr (VI) in simulated groundwater. Water, Air, and Soil Pollution, 230, 1-14.
Zhu, K., Gao, Y., Tan, X., & Chen, C. (2016). Polyaniline-modified Mg/Al layered double hydroxide composites and their application in efficient removal of Cr (VI). ACS Sustainable Chemistry and Engineering, 4, 4361-4369.
Zhu, S., Ho, S. H., Huang, X., Wang, D., Yang, F., Wang, L., ... and Ma, F. (2017). Magnetic nanoscale zerovalent iron assisted biochar: interfacial chemical behaviors and heavy metals remediation performance. ACS Sustainable Chemistry and Engineering, 5, 9673-9682.